Organotransition Metal Chemistry

From Bonding to Catalysis

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Author: John Frederick Hartwig

Publisher: Univ Science Books

ISBN: N.A

Category: Science

Page: 1127

View: 7294

Based on the classic text 'Principles and Applications of Organotransition Metal Chemistry', this book provides a comprehensive update of this vital area. It covers the most important developments in the field over the last 20 years.

Fundamentals of Organometallic Catalysis

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Author: Dirk Steinborn

Publisher: John Wiley & Sons

ISBN: 3527327177

Category: Science

Page: 456

View: 3179

Catalysis, the basic principle for overcoming the kinetic inhibition of chemical reactions, is fundamental in chemistry. In particular, organometallic catalysis plays an overwhelming role in both research and industry. It opens the way to entirely novel synthetic methods and finds widespread applications ranging from mass-production of everyday polymers to stereocontrolled synthesis of bioactive chemicals used as pharmaceuticals and agrochemicals. The targeted development of improved and novel catalysts demands understanding of the relationships between their structures and catalytic properties. Accordingly, this textbook offers the reader a fundamental understanding of the course of organometallic-catalyzed reactions, starting at the molecular level. The initial chapters explain the principles of catalysis and the elementary steps in organometallic catalysis. The book then explores important organometallic-catalyzed reactions, with a focus on mechanism. Current developments are emphasized throughout. Asymmetric synthesis is covered in depth. Finally, the book examines the catalytic behavior of particular metalloenzymes. A look at nitrogen fixation offers a comparative examination of the three major areas of catalysis - homogeneous, heterogeneous, and enzymatic. In addition to problems, the textbook offers solutions, making the book an invaluable learning tool. It is a must-have for advanced students in chemistry and biochemistry, as well as for inorganic and organic chemists, for those working with organometallics, and for those specializing in catalysis.

The Chemical Bond III

100 years old and getting stronger

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Author: D. Michael P. Mingos

Publisher: Springer

ISBN: 331935146X

Category: Science

Page: 205

View: 868

The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors

Homogeneous Catalysis

Mechanisms and Industrial Applications

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Author: Sumit Bhaduri,Doble Mukesh

Publisher: John Wiley & Sons

ISBN: 1118872517

Category: Science

Page: 288

View: 5970

Over the last decade, the area of homogeneous catalysis withtransition metal has grown in great scientific interest andtechnological promise, with research in this area earning threeNobel Prizes and filing thousands of patents relating tometallocene and non-metallocene single site catalysts, asymmetriccatalysis, carbon-carbon bond forming metathesis and cross couplingreactions. This text explains these new developments in a unified, cogent, andcomprehensible manner while also detailing earlier discoveries andthe fundamentals of homogeneous catalysis. Serving as a self-studyguide for students and all chemists seeking to gain entry into thisfield, it can also be used by experienced researchers from bothacademia and industry for referring to leading state of the artreview articles and patents, and also as a quick self-study manualin an area that is outside their immediate expertise. The bookfeatures: • Topics including renewable feed stocks (biofuel,glycerol), carbon dioxide based processes (polycarbonates),fluorous solvents, ionic liquid, hydroformylation, polymerization,oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry,homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (casestudies), and examples from proven industrial processes with cleardiscussions on environmental and techno-commercial issues • Extensive references to cutting edge research withapplication potential and leading patents • Tables and illustrations to help explain difficultconcepts

Organotransition Metal Chemistry A Mechanistic Approach

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Author: Richard Heck

Publisher: Elsevier

ISBN: 0323154700

Category: Science

Page: 350

View: 2239

Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.

Organotransition Metal Chemistry: Applications to Organic Synthesis

Applications to Organic Synthesis

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Author: S. G. Davies

Publisher: Elsevier

ISBN: 1483285847

Category: Science

Page: 430

View: 7335

Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Organotransition Metal Chemistry

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Author: Anthony F. Hill,A. F. Hill

Publisher: Royal Society of Chemistry

ISBN: 9780854046225

Category: Education

Page: 185

View: 6770

This book aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists in a variety of industry sectors.

Organotransition Metal Chemistry

Fundamental Concepts and Applications

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Author: Akio Yamamoto

Publisher: Wiley-Interscience

ISBN: N.A

Category: Science

Page: 455

View: 321

A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.