Organic Reaction Mechanisms

40 Solved Cases

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Author: Mar Gomez-Gallego,Miguel A. Sierra

Publisher: Springer Science & Business Media

ISBN: 3642187889

Category: Science

Page: 290

View: 9253

Organic Reaction Mechanisms shows readers how to interpret the experimental data obtained from an organic reaction, and specifically how an organic reaction mechanism can be considered or rejected based on the analysis of the experimental evidence. Whilst examining a series of selected examples of mechanisms, the text focuses on real cases and discusses them in detail. The examples are arranged to elucidate key aspects of organic reaction mechanisms. The authors employ all the types of information that the authors of the original work considered useful and necessary, including spectroscopic data, kinetic and thermodynamic data, isotopic labelling and organic reactivity. The book makes an excellent primer for advanced undergraduates in chemistry who are preparing for exams and is also useful for graduate students and instructors.

Determination of organic reaction mechanisms

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Author: Barry Keith Carpenter

Publisher: Wiley-Interscience

ISBN: N.A

Category: Science

Page: 247

View: 3433

This practical handbook presents concise descriptions of the most commonly employed experimental techniques for studying reaction mechanisms in organic chemistry. For each technique, all necessary theoretical background is covered, and at least one example of its application--taken from the research literature--is described in detail.

Organic Reaction Mechanisms

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Author: V. K. Ahluwalia,Rakesh Kumar Parashar

Publisher: Alpha Science Int'l Ltd.

ISBN: 9781842652367

Category: Science

Page: 639

View: 6401

This book, written explicitly for graduate and postgraduate students of chemistry, provides an extensive coverage of various organic reaction and rearrangements with emphasis on there application in synthesis. A summary of oxidation and reduction of organic compounds is given in tabular form (correlation tables) for the convenience of students. The most commonly encountered reaction intermediates are dealt with. Applications of organic reagents illustrated with examples and problems at the end of each chapter will enable students to evaluate their understanding of the topic.

Organic Reaction Mechanisms

A Step by Step Approach, Second Edition

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Author: Michael Edenborough

Publisher: CRC Press

ISBN: 1351989707

Category: Science

Page: 500

View: 9958

This text is designed to teach students how to write organic reaction mechanisms. It starts from the absolute basics - counting the numbers of electrons around a simple atom. Then, in small steps, the text progresses to advanced mechanisms. the end, all the major mechanistic routes have been covered. The text is in the form of interactive sections, which are designed to facilitate the assimilation of the information conveyed, so that by the end the student should already know the contents without the need for extensive revision.

Mechanisms of Organic Reactions

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Author: Howard Maskill

Publisher: Oxford University Press

ISBN: 9780198558224

Category: Science

Page: 96

View: 4670

Focusing on organic reactions, this text begins by introducing modern technology, definitions, and concepts of mechanisms and reactivity. The following four chapters are accounts of the mechanisms of four of the main classes of reactions of aliphatic compounds.

Writing Reaction Mechanisms in Organic Chemistry

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Author: Audrey Miller,Philippa H. Solomon

Publisher: Academic Press

ISBN: 9780124967120

Category: Science

Page: 471

View: 5077

Writing Reaction Mechanisms in Organic Chemistry, Second Edition, is an invaluable guide to charting the movements of atoms and electrons in the reactions of organic molecules. Miller and Solomon illustrate that understanding organic reactions is based on applying general principles rather than the rote memorization of unrelated processes, and, in turn, emphasize that writing mechanisms is a practical method of applying knowledge of previously encountered reactions and reaction conditions to new reactions. Students and research chemists alike will find this book useful in providing a method of organizing and synthesizing an oftentimes overwhelming quantity of information into a set of general principles and guidelines for determining and describing organic reaction mechanisms. * Essential for those students who need to have mechanisms explained in greater detail than most organic chemistry textbooks provide. * Illustrated with hundreds of chemical structures * Extensively rewritten and reorganized to make the presentation and format even easier for students to use * Contains many problem sets and answers to all problems to help students work through general principles and applications * Appendixes have been added to this edition that contain easily referenced information on Lewis structures, symbols for chemical notation, and the relative acidities of common substances

How To Solve Organic Reaction Mechanisms

A Stepwise Approach

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Author: Mark G. Moloney

Publisher: John Wiley & Sons

ISBN: 111840159X

Category: Science

Page: 248

View: 5006

How To Solve Organic Reaction Mechanisms: A Stepwise Approach is an upgraded and much–expanded sequel to the bestselling text Reaction Mechanisms at a Glance. This book takes a unique approach to show that a general problem–solving strategy is applicable to many of the common reactions of organic chemistry, demonstrating that logical and stepwise reasoning, in combination with a good understanding of the fundamentals, is a powerful tool to apply to the solution of problems. Sub–divided by functional group, the book uses a check–list approach to problem–solving using mechanistic organic chemistry as its basis. Each mechanistic problem is presented as a two–page spread; the left–hand page introduces the problem and provides a stepwise procedure for working through the reaction mechanisms, with helpful hints about the underlying chemistry. The right–hand page contains the full worked solution and summary. This revised edition includes the following updates: • A new chapter which applies the problem solving strategy to ligand coupling reactions using transition metals • Much–expanded set of fully worked problems • Over 40 further problems (with answers for tutors) for use in tutorials How To Solve Organic Reaction Mechanisms: A Stepwise Approach is an essential workbook for all students studying organic chemistry, and a useful aide for teachers of undergraduate organic chemistry to use in their tutorials.

Organic Reaction Mechanisms 2013

An Annual Survey Covering the Literature Dated January to December 2013

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Author: A. C. Knipe

Publisher: John Wiley & Sons

ISBN: 1118707869

Category: Science

Page: 728

View: 1708

Organic Reaction Mechanisms 2013, the 49th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2013. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.

The Art of Writing Reasonable Organic Reaction Mechanisms

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Author: Robert B. Grossman

Publisher: Springer Science & Business Media

ISBN: 0387954686

Category: Science

Page: 360

View: 8695

Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

Advanced Problems in Organic Reaction Mechanisms

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Author: Alexander McKillop

Publisher: Elsevier

ISBN: 9780080432557

Category: Science

Page: 153

View: 2590

This book is a collection of 300 problems which challenge the user to devise reasonable mechanistic interpretations for sets of experimental observations. Almost all of the problems are taken from the literature of the last twenty years. Each is a separate entity, although similar mechanistic themes occur in several quite different problems. Answers are not given, nor are references to the original literature. The user who fails to solve a particular problem and reaches an appropriate level of frustration should be able, relatively quickly, to locate the original literature from the information given in the problem. For senior undergraduate and graduate students of organic chemistry and all teachers of organic chemistry.

Organic Reactions And Their Mechanisms

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Author: P S Kalsi

Publisher: New Age International

ISBN: 9788122412680

Category:

Page: 666

View: 6610

This Revised Edition Includes Several New Topics To Make The Treatment More Comprehensive And Contemporary. The Exposition In Several Chapters Has Also Been Recast To Facilitate An Easier Understanding Of The Subject. * Molecular Orbital And Bonding Thoroughly Explained. * Resonance Structures And Allylic Systems Included. * Organic Acids And Bases Explained In Detail With Additional Examples. * Discussion Of Organic Reactions Considerably Expanded. * Various Additional Dimensions Of Photochemistry Highlighted. * A New Chapter On Special Topics Included.With Its Clear And Systematic Presentation, This Is An Essential Text For B.Sc. And M.Sc. Chemistry Students.

Challenging Problems in Organic Reaction Mechanisms

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Author: Darshan Ranganathan

Publisher: Elsevier

ISBN: 0323160719

Category: Science

Page: 174

View: 4441

Challenging Problems in Organic Reaction Mechanisms explores the problems encountered in the study of the various facets of organic chemistry, including syntheses, reactions, reagents, and reaction mechanisms. Each problem describes the starting material, the conditions of the reaction, and the product, followed by the reference to the original publication. This permits the reader to solve the problem independently and then compare the results with those presented in the literature. The example problems are arranged in such a manner that each page is balanced. The utility of this collection has been enhanced by inclusion of, first, a ""compound index"" which allows rapid identification of rearrangements associated with a specific substrate; second, a ""reaction-type index"" which unifies reactions associated with a particular transition state and brings into focus the usefulness of Woodward-Hoffman notations in understanding bond formation and cleavage; and, finally, a ""problem classification index"". This work is of great value to organic chemists and researchers and organic chemistry teachers and students.

Introductory Organic Reaction Mechanisms: A color-coded approach to arrow pushing

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Author: Michael Leonard

Publisher: Lulu.com

ISBN: 1304515893

Category: Science

Page: 364

View: 1692

To master Organic Chemistry, it is essential to master mechanism. This book uses a novel approach to help you better understand the mechanisms of 80 common organic reactions. Each one is color coded so that you can clearly see the changes that take place during the reaction. The electrons involved in the mechanism are color coded, as are the arrows originating from those electrons and the bonds or lone pairs formed by them in the intermediates and product. As a result, you can trace specific pairs of electrons through an entire transformation. The description of what each mechanistic arrow means is color coded correspondingly so that it is easy to match up the text with the relevant portion of a reaction diagram.

Further Challenging Problems in Organic Reaction Mechanisms

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Author: Darshan Ranganathan

Publisher: Elsevier

ISBN: 032315719X

Category: Science

Page: 296

View: 2736

Further Challenging Problems in Organic Reaction Mechanisms explores the problems encountered in the study of the various facets of organic chemistry, including syntheses, reactions, reagents, and reaction mechanisms. Each problem describes the starting material, the conditions of the reaction, and the product, followed by the reference to the original publication. This permits the reader to solve the problem, either independently or with guidance from the Pathways and Pointers provided, and then compare the results with those presented in the literature. This work is of great value to organic chemists and researchers and organic chemistry teachers and students.

Organic Reaction Mechanisms 2014

An Annual Survey Covering the Literature Dated January to December 2014

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Author: A. C. Knipe

Publisher: John Wiley & Sons

ISBN: 1118941799

Category: Science

Page: 1024

View: 2324

Organic Reaction Mechanisms 2014, the 50th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2014. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. This volume includes a 5-year cumulative index.

Advanced Organic Chemistry

Reaction Mechanisms

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Author: Reinhard Bruckner

Publisher: Academic Press

ISBN: 9780121381103

Category: Science

Page: 636

View: 6580

Contents - Radical Substitution Reactions at the Saturated C Atom. Nucleophilic Substitution Reactions at the Saturated C Atom. Additions to the Olefinic C=C Double Bond. Eliminations Substitution Reactions on Aromatic Compounds. Nucleophilic Substitution Reactions (Except Through Enolates) on the Carboxyl Carbon. Additions of Heteroatom Nucleophiles to Heterocumulenes. Additions of Heteroatom Nucleophiles to Carbonyl Compounds and Their Secondary Reactions. Addition of H Nucleophiles and Metal Organyls to Carbonyl Compounds. Reaction of Ylides with Saturated or Unsaturated Carbonyl Compounds. Chemistry of the Alkaline Earth Metal Enolates. Rearrangements. Thermal Cycloadditions. Transition Metal-Mediated Alkenylations, Arylations and Alkynylations. Oxidations and Reductions.

Organic Reaction Mechanisms 2003

An annual survey covering the literature dated January to December 2003

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Author: A. C. Knipe

Publisher: John Wiley & Sons

ISBN: 0470061235

Category: Science

Page: 644

View: 7386

The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 2003 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 2003. The 39th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.